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A comparative study of the photo-catalytic performance of amorphous and nano-crystalline TiO2

A. MOLEA1, V. POPESCU1,* , N. A. ROWSON2

Affiliation

  1. Technical University of Cluj-Napoca, Faculty of Material and Environmental Engineering, Physics and Chemistry Department, No.103-105 Muncii avenue, 400641 Cluj-Napoca, Romania
  2. University of Birmingham, School of Chemical Engineering, Edgbaston Birmingham B15 2TT, United Kingdom

Abstract

Titanium dioxide powders with photocatalytic properties were obtained by a simple hydrolysis method, using an inorganic precursor. The effect of the annealing temperature on the formation and subsequent photocatalytic activity has been studied. The powders were characterized by X-ray diffraction, Raman and UV-Vis spectrometry in order to emphasise the structural and optical properties. The photo-catalytic performance of the powders by degradation of Methylene Blue under low intensity UVA and visible radiation were also quantified. The amorphous powder exhibits higher photo-catalytic activity than the equivalent anatase phase. The degradation efficiency of the dye in presence of the amorphous catalyst was 43%..

Keywords

TiO2 catalyst, Amorphous, Nano-crystalline phases, Photo-catalytic performance.

Citation

A. MOLEA, V. POPESCU, N. A. ROWSON, A comparative study of the photo-catalytic performance of amorphous and nano-crystalline TiO2, Optoelectronics and Advanced Materials - Rapid Communications, 9, 3-4, March-April 2015, pp.431-435 (2015).

Submitted at: Sept. 6, 2014

Accepted at: March 19, 2015