Abstract
Cr-doped ZnO powders were synthesized successfully with different doping concentration by sol–gel method. The structural, optical and magnetic properties of the samples were investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) and vibrating sample magnetometer (VSM). XRD and XPS indicate that the Cr ions are at least partially substitutionally incorporated into the crystal lattice of ZnO. The saturation doping concentration of
Cr in ZnO lattice is estimated to be less than 7.0 at %. Magnetic measurements indicated that the Cr doped ZnO samples
show ferromagnetic behavior at room temperature and the ferro magnetism decreases with increasing Cr doping
concentration. PL measurements sho wed that Zn1xCrxO powders with the increased of Cr concentration exhibited obvious
blue shift and the intensity of the green emission band is enhanced..
Keywords
Diluted magnetic semiconductors, Ferrom agnetism, Optical properties.
Citation
SHI FENG NIU, JIA HONG ZHENG, A study of structural, magnetic and optical properties of Zn1xCrxO, Optoelectronics and Advanced Materials - Rapid Communications, 7, 1-2, January-February 2013, pp.104-109 (2013).
Submitted at: July 2, 2012
Accepted at: Feb. 20, 2013