Abstract
Layered material
α LiNbWO 6 was prepared by solid state method , HNbWO 6 Fe 1/3 NbWO 6 and HNbWO 6 /Fe 2 O 3 SO 4
2 w ere
prepared by the method s such as ion exchange, intercalation and impregnation based on the parent material The phase
structures, morphologies, skeleton characteristics and acidic properti e s of the materials w ere characterized by powder X ray
diffraction XRD ), scanning e lectron microscope (SEM), f ourier transform infrared spectroscopy (FT IR) and NH 3
temperature programmed desorption ( NH 3 TPD Results show that t he garllery height of the materials var y with
the difference interlayer species and t he acid strength follows the order HNbWO 6 /Fe 2 O 3 SO 4
2 HNbWO 6 > Fe 1/3 NbWO 6
HNbWO 6 /Fe 2 O 3 SO 4
2 shows the best catalytic activity and the highest selectivity for toluene nitration ..
Keywords
Modified α LiNbWO 6 P hase s tr ucture s Acidic properti es Toluene nitration R egioselective.
Citation
YUAN WANG, RUI DONG, AN LI, LIFANG HU, JIE HE, Characterization of modified α LiNbWO 6 layered material s and their catalytic performance for toluene nitration, Optoelectronics and Advanced Materials - Rapid Communications, 10, 1-2, January-February 2016, pp.102-107 (2016).
Submitted at: Sept. 22, 2014
Accepted at: Feb. 10, 2016