Abstract
Specific retention volume, 0 Vg of benzene, ethyl benzene, n-propyl benzene, isopropyl benzene and chlorobenzene on
poly(4-methyl-1-pentene) were obtained by inverse gas chromatography at temperature range in o
C of 240 and 280. The
Flory-Huggins polymer-solvent interaction parameters were determined. The solubility parameter of poly(4-methyl-1-
pentene), δ2 was determined as 7.64 (cal/cm3
)
1/2 at room temperature by extrapolation of the values obtained at high
temperature. Then, dielectric constant and dipole moment of poly(4-methyl-1-pentene) were calculated by means of
solubility parameter determined experimentally. The data found in this study are in agreement compared with the ones
obtained in the literature.
Keywords
Poly(4-methyl-1-pentene), inverse gas chromatography, Flory-Huggins interaction parameter, Solubility parameter of
polymer, Dielectric constant.
Citation
O. YAZICI, F. CAKAR, O. CANKURTARAN, F. KARAMAN, Determination of dielectric properties by solubility parameter of poly(4-methyl -1-pentene), Optoelectronics and Advanced Materials - Rapid Communications, 2, 10, October 2008, pp.655-658 (2008).
Submitted at: April 7, 2008
Accepted at: Oct. 2, 2008