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Enhanced PEDOT: PSS films by acetonitrile co-solvents and their application on polymer solar cells

GUILIN LIU1, YING GUO2, HUAXIN ZHU2, HUIMIN YAN2, BINGJIE ZHU2, GUOHUA LI2,3,*

Affiliation

  1. School of Internet of Things Engineering, Wuxi 214122, China
  2. School of Science, Jiangnan University, Wuxi 214122, China
  3. Jiangsu (Suntech) Institute for Photovoltaic Technology, Wuxi 214028, China

Abstract

The application of Acetonitrile (ACN) on Polymer Solar Cells (PSCs) was investigated in this paper. The conductivity of PEDOT: PS S was significantly enhanced compared with that of untreated samples. The PEDOT: PSS was mixed with freshly prepared co solvents of ACN and De Ionized water . Meanwhile, the Power Conversion Efficiency (PCE) of PSCs was improved by a freshly prepared co sol vent treatment. The PCE of co solvent treated devices achieved 1.27% while the untreated one was only 0.3%. However, expired co solvents were found to be negative to PSCs because of ACN hydrolysis. The PCE of PSCs based on hydrolyzed co solvents was lower than 0.01%. It was found that the H and NH 4 ions generated from ACN aggregates the PEDOT: PSS and roughs the surface of PEDOT: PSS thin films. Meanwhile , Indium ion s was dissolved and transported to the PEODT: PSS surface by the acetic acid could be anot her possibility of the performance decrease . Although the conductivity dramatically increased to 230S cm 1 the series resistance simultaneously increased over 1.5×103 Ω·cm2, leads to a great loss of current output. Because of that, charges could not be transport ed to the electrodes since they are recombined at the PEDOT: PSS surface..

Keywords

Polymer Solar Cells, PEDOT:PSS, Doping, Hydrolysis.

Citation

GUILIN LIU, YING GUO, HUAXIN ZHU, HUIMIN YAN, BINGJIE ZHU, GUOHUA LI, Enhanced PEDOT: PSS films by acetonitrile co-solvents and their application on polymer solar cells, Optoelectronics and Advanced Materials - Rapid Communications, 10, 9-10, September-October 2016, pp.693-699 (2016).

Submitted at: Dec. 17, 2014

Accepted at: Sept. 29, 2016