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Sol gel loading of Sm 2 Ti 2 O 7 on HZSM 5 zeolite for enhanced photocatalytic activity

JUN YAO1, YANGYANG CHEN1, LING DU1, WENJIE ZHANG1,*

Affiliation

  1. School of science , Shenyang Ligong University, Shenyang 110159, China

Abstract

Sm 2 Ti 2 O 7 /HZSM 5 composite material was prepared by s ol gel method. Pyrochlore structured Sm 2 Ti 2 O 7 formed in the unloaded Sm 2 Ti 2 O 7 and Sm 2 Ti 2 O 7 /HZSM 5. EDS mappings of Sm and Ti prove the loading of Sm 2 Ti 2 O 7 on the surface of HZSM 5. Typical absorptions of Sm 2 Ti 2 O 7 appear in the infrared spectra of the Sm 2 Ti 2 O 7 /HZSM 5 samples calcined at temperature over 800 o C . The maximum amount of hydroxyl radicals is produced on the Sm 2 Ti 2 O 7 /HZSM 5 sample calcined at 800 o C . E CB and E VB of Sm 2 Ti 2 O 7 /HZSM 5 at 800 o C are 0.66 V and 2.77 V, respectively. The supported Sm 2 Ti 2 O 7 /HZSM 5 has much improved activity as compared to the unloaded Sm 2 Ti 2 O 7.

Keywords

Sm 2 Ti 2 O 7 , HZSM 5 , S ol gel, P hotocatalytic, D egradation.

Citation

JUN YAO, YANGYANG CHEN, LING DU, WENJIE ZHANG, Sol gel loading of Sm 2 Ti 2 O 7 on HZSM 5 zeolite for enhanced photocatalytic activity, Optoelectronics and Advanced Materials - Rapid Communications, 13, 1-2, January-February 2019, pp.136-140 (2019).

Submitted at: Dec. 4, 2017

Accepted at: Feb. 12, 2019