Abstract
The nanocrystalline La2/3Ca1/3MnO3 samples were prepared by sol-gel method and were sintered at different temperatures ranging from 600ºC to 1000ºC. It has been found that the magnetic and transport properties of the samples strongly depend on the sintering temperature. Decreasing the sintering temperature causes a substantial decrease in insulator-metal transition temperature (TIM) and enhancement in resistivity. Reduction in magnetization and slight decrease in paramagnetic-ferromagnetic (PM-FM) transition temperatures (Tc) has been observed as the sintering temperature decreases. The MR at T<Tc increases on decreasing the sintering temperature as well as on increasing the applied magnetic field. However, at/around Tc the intrinsic contribution of MR occurs which is more in the samples sintered at higher temperatures. These variations in MR are explained by enhanced spin polarized tunneling by assuming the increase of grain boundary contribution as the sintering temperature decreases.
Keywords
Electrical transport, Nanocrystalline, Grain boundaries.
Citation
A. GAUR, U. KR. GAUR, K. YADAV, G. D. VARMA, Study of structural, magnetic and magneto-transport properties of nanocrystalline La2/3Ca1/3MnO3 manganite, Optoelectronics and Advanced Materials - Rapid Communications, 4, 7, July 2010, pp.989-994 (2010).
Submitted at: May 31, 2010
Accepted at: July 14, 2010