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Study on nano-Al2O3 modified by supercritical fluid

CHEN YUFEI1,2,* , DAI QIWANG2, TAN JUNYAN2, ZHANG QINGYU2

Affiliation

  1. Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin, 150080, China
  2. The College of Materials Science and Engineering, Harbin University of Science and Technology, Harbin, 150040, China

Abstract

Nano-Al2O3 was modified by supercritical ethanol and supercritical water, respectively. The mechanism between supercritical fluid and nano-Al2O3 was analyzed, and the microstructure of nano-Al2O3 was investigated. The mechanism between supercritical fluid and nano-Al2O3 was that the hydrogen bond between the molecules of fluid became attenuating, when the fluid was in the supercritical state. The surface of nano-Al2O3 was coated with fluid molecules through the bonding between the hydroxyl of nano-Al2O3 and fluid molecules. The effect of surface modification of nano-Al2O3 was the best when the nano-Al2O3 was modified by supercritical ethanol and the processing time was 5min..

Keywords

Supercritical water, Supercritical ethanol, Hydrogen bond, Nano-Al2O3.

Citation

CHEN YUFEI, DAI QIWANG, TAN JUNYAN, ZHANG QINGYU, Study on nano-Al2O3 modified by supercritical fluid, Optoelectronics and Advanced Materials - Rapid Communications, 8, 9-10, September-October 2014, pp.925-929 (2014).

Submitted at: June 20, 2014

Accepted at: Sept. 11, 2014