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Variable self-assembled micronanostructures of Bis(8-hydroxyquinolato)-urushiolato Aluminum (III) by the reverse breath figure method

WEIBIN BAI1,* , YANLIAN XU2, ZHAOQIAO TONG1, JINHUO LIN1,2

Affiliation

  1. College of Chemistry and Material Science, Fujian Normal University, Fuzhou 350007, PR China
  2. Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, PR China

Abstract

A novel urushiol-based complex bis(8-hydroxyquinolato)-urushiolato Aluminum (III) (AlUQ2) has been successfully synthesized and characterized by FT-IR and Elemental analysis. The optical properties are investigated by UV-Vis and fluorescent spectra, and the result shows it emits green light with the wavelength at about 520 nm. The self-assembled ordered structures formed by layered nano-rods with the diameter of approximate 100 nm and the length of 300 nm via the reverse breath figure method, can be observed by SEM. By changing different solvents and vapor atmosphere, the micronanostructures of AlUQ2 with variable morphology can self-assemble, obtaining dispersed nano-plates and aggregated nano-rods..

Keywords

Microstructure, Multilayer structure, Reverse breath figure method, Fluorescence.

Citation

WEIBIN BAI, YANLIAN XU, ZHAOQIAO TONG, JINHUO LIN, Variable self-assembled micronanostructures of Bis(8-hydroxyquinolato)-urushiolato Aluminum (III) by the reverse breath figure method, Optoelectronics and Advanced Materials - Rapid Communications, 5, 1, January 2011, pp.22-24 (2011).

Submitted at: Nov. 6, 2010

Accepted at: Jan. 26, 2011