Abstract
In this paper, we present the results of the theoretical evaluation of the vibronic linear coupling constants for the V3+ doped
in Li(Al,Ga)O2 crystal. In the case of a tetrahedral complexs V3+: Li(Al,Ga)O2 the interaction with full symmetric A1, tetragonal E and two trigonal vibrations T2 (1) and T2 (2) are considered. The liniar vibronic coupling constants are numerically
calculated for each case of the Jahn-Teller interactions and all considered types such interaction are expected to give information on the new peculiarities of the absorption and emission bands, as well as of non-radiative transitions between
the electronic states of impurity ions..
Keywords
Vibronic coupling constants, Crystal field theory, 3d-ions.
Citation
E.-L. ANDREICI, N. M. AVRAM, Vibronic coupling constants for V3+ doped in Li(Al,Ga)O2 crystals, Optoelectronics and Advanced Materials - Rapid Communications, 6, 7-8, July-August 2012, pp.721-722 (2012).
Submitted at: July 3, 2012
Accepted at: July 19, 2012